Zambia Archives and Libraries
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The British National Archives have references to some records relating to Northern Rhodesia, including papers related to the missionary and explorer David Livingstone and James Young, a chemist.
Livingstone Museum in Zambia has artifacts relating to David Livingstone, including personal papers.
The National Archives website used to be at zambiarchives.org. Their offices are on Government Road, Ridgeway, Lusaka, next to the post office.
The University of London School of Oriental and African Studies has many papers relating to missionaries.
The National Library of Scotland has papers relating to David Livingstone.
For some more archive references, see the British National Archives.